Studies of the polyanions and polycations by Glauber's-salt cryoscopy. Part II. Polycations of uranium

Abstract

Depression in the transition temperature of Glauber's salt owing to the presence of UO₂²⁺ and other polycations of uranium formed by the hydrolysis of UO₂²⁺ have been measured at different pH. The average degree of condensation calculated from these measurements appear to confirm the existence of the polycations with the general formula UO₂[(OH)₂UO₂]_n²⁺ with increasing rapidly above pH 5.