A new and convenient route to complexes of the type trans-[lrX(CO)L2](X = halogen; L = tertiary phosphine or tertiary arsine) is described. Some reactions of trans-[lrX(CO)(PEt2Ph)2](X = Cl, Br) are also described including metathesis, and addition of hydrogen halides, methyl bromide, acyl chlorides, and allyl chloride. Dipole moments and infrared results are given.
J. Chatt, N. P. Johnson and B. L. Shaw, J. Chem. Soc. A, 1967, 604 DOI: 10.1039/J19670000604
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