The visible and ultraviolet spectra of trigonal bipyramidal complexes of d6-, d7-, and d8-metal ions
Abstract
Two-parameter ligand-field calculations for trigonal bipyramidal complexes of d6-, d7-, and d8-metal ions have been carried out by use of tensor operator theory. The energy-level diagrams obtained have been used for the assignment of the spectra of complexes [MX(QP)]+[M = Fe, Co, and Ni; QP = tris-(o-diphenylphosphinophenyl)phosphine].
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