The nickel(II), copper(II), and zinc(II) complexes of the chelated enediols 2,2′-pyridoin and 6,6′-dimethyl-2,2′-pyridoin have been prepared and characterised. They are shown to be co-ordination polymers with minimum molecular weights in the range 2500–3000. The magnetic, spectral, and thermal properties are discussed, and related to the stereochemistry of the metal atom in the complexes.
M. Brierley and W. J. Geary, J. Chem. Soc. A, 1967, 321 DOI: 10.1039/J19670000321
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