The dependence of the value of the acidity constant of HSO–4 on the assumed value of the mean ionic diameter, established experimentally by Covington et al., is explained quantitatively. An analogous, but much smaller, effect on the acidity constant of H3PO4, observed by Bates, is explained semi-quantitatively.
E. A. Guggenheim, Trans. Faraday Soc., 1966, 62, 2750 DOI: 10.1039/TF9666202750
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