The standard enthalpy change of the reaction AOH(g)→A(g)+OH(g) has been measured in H2+O2+N2 flames for all alkali metals A through a procedure based upon the third law. Values obtained for ΔH°° are 101±2, 77±4, 81±2, 83±2 and 91±3 kcal/mole for A = Li, Na, K, Rb and Cs respectively.
D. E. Jensen and P. J. Padley, Trans. Faraday Soc., 1966, 62, 2132 DOI: 10.1039/TF9666202132
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