Volume 62, 1966
From the journal:

Transactions of the Faraday Society

Dissociation energy of NaO2

M. J. McEwan  and  L. F. Phillips  

Abstract

Photometric observations on traces of alkali metals in lean H2+N2+O2 flames at ca. 2000°K have confirmed that significant amounts of NaO2 are formed by the reaction, Na+O2+M → NaO2+M. From measured values of the equilibrium constant for this reaction the dissociation energy [graphic omitted] has been calculated as 65±3 kcal mole–1. Results for potassium in these flames yield values of the termolecular rate constant for KO2 formation, but do not yield equilibrium data because of the greater stability of KO2.

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Article information

DOI
https://doi.org/10.1039/TF9666201717
Article type
Paper

Trans. Faraday Soc., 1966,62, 1717-1720

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Dissociation energy of NaO2

M. J. McEwan and L. F. Phillips, Trans. Faraday Soc., 1966, 62, 1717 DOI: 10.1039/TF9666201717

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