The far infra-red spectra of n-propyl chloride, bromide and iodide have been examined to 60 cm–1 in the vapour, liquid and crystalline phases; these permit the vibrational assignment to be completed. The influence of the phase on the skeletal torsion frequency is discussed in the light of theories of the origin of torsional barriers.
K. Radcliffe and J. L. Wood, Trans. Faraday Soc., 1966, 62, 1678 DOI: 10.1039/TF9666201678
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