The structure and stereochemistry of thymine dimer, obtained by ultraviolet irradiation of a frozen, aqueous solution of thymine, is determined by its transformation into an isomer shown to be a derivative of 3,5,9-triazatricyclo-[5,3,0,02,6]decane of cis-syn-cis configuration.
G. M. Blackburn and R. J. H. Davies, J. Chem. Soc. C, 1966, 2239 DOI: 10.1039/J39660002239
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