Issue 0, 1966
From the journal:

Journal of the Chemical Society C: Organic

Natural acetylenes. Part XXIII. A C18 polyacetylenic keto-aldehyde related to falcarinone from an Umbellifer (Pastinaca sativa L.)

SirEwart R. H. Jones,   S. Safe  and  V. Thaller  

Abstract

The structure of the polyacetylenic keto-aldehyde {H2C[double bond, length as m-dash]CH·CO·[C[triple bond, length as m-dash]C]2·CH2·CH[graphic omitted]CH·[CH2]7·CHO} has been determined. It is the first C18 polyacetylene to be isolated from a plant (Pastinaca sativa L.) of the main polyacetylene-producing families. Its occurrence almost certainly establishes the derivation of the C17 falcarinone and related compounds and is in harmony with Bu'Lock's hypothesis for the biogenesis of the natural acetylenes.

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Article information

DOI
https://doi.org/10.1039/J39660001220
Article type
Paper

J. Chem. Soc. C, 1966, 1220-1221

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Natural acetylenes. Part XXIII. A C18 polyacetylenic keto-aldehyde related to falcarinone from an Umbellifer (Pastinaca sativa L.)

E. R. H. Jones, S. Safe and V. Thaller, J. Chem. Soc. C, 1966, 1220 DOI: 10.1039/J39660001220

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