Issue 0, 1966

The addition of thiols to 5,6-dimethylenenorborn-2-ene, and its reactivity towards thiol addition relative to the reactivity of other bridged polycyclic olefins

Abstract

The products formed on the addition of thiophenol to 5,6-dimethylenenorborn-2-ene have been identified by means of nuclear magnetic resonance spectroscopy, and possible pathways of product formation are discussed. The addition of p-thiocresol and methanethiol is briefly reported. The relative reactivities of 5,6-dimethylenenorborn-2-ene and various other bridged polycyclic olefins towards reaction with (a) thiophenol and (b) methyl mercaptoacetate have been determined, and the significance of the results reviewed.

Article information

Article type
Paper

J. Chem. Soc. C, 1966, 1045-1050

The addition of thiols to 5,6-dimethylenenorborn-2-ene, and its reactivity towards thiol addition relative to the reactivity of other bridged polycyclic olefins

J. A. Claisse and D. I. Davies, J. Chem. Soc. C, 1966, 1045 DOI: 10.1039/J39660001045

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