Issue 0, 1966

Surface problems in kinetic studies of the gas-phase pyrolyses of alkyl halides. Part I. Reaction-vessel coatings of pyrolytic carbon

Abstract

The unpaired electron content and reactivity of carbons produced by the pyrolyses of allyl bromide, cis-but-2-ene, isobutene, and ethyl bromide have been examined by e.s.r. spectroscopy. It is shown that these carbons do not catalyse the unimolecular elimination of hydrogen bromide from isopropyl bromide and n-butyl bromide.

Article information

Article type
Paper

J. Chem. Soc. B, 1966, 713-716

Surface problems in kinetic studies of the gas-phase pyrolyses of alkyl halides. Part I. Reaction-vessel coatings of pyrolytic carbon

M. R. Bridge and J. L. Holmes, J. Chem. Soc. B, 1966, 713 DOI: 10.1039/J29660000713

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