Kinetics of peroxydisulphate oxidation of several substituted tris-1,10-phenanthroline and tris-2,2′-bipyridyl complexes of iron(II) have been studied. Activation energies and frequency factors have been determined. Substituent effects on these parameters are described, and the mechanism of the oxidation discussed.
J. Burgess and R. H. Prince, J. Chem. Soc. A, 1966, 1772 DOI: 10.1039/J19660001772
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