Issue 0, 1966
From the journal:

Journal of the Chemical Society A: Inorganic, Physical, Theoretical


Ionisation and dissociation of trityl perchlorate in some non-aqueous solvents

W. R. Longworth  and  C. P. Mason  

Abstract

The infrared spectrum of crystalline trityl perchlorate shows it to be ionic in the solid state. Spectrophotometric study of its solutions reveals that it is completely ionised in chloroform, methylene dichloride, 1,1-dichloroethane, and 1,2-dichloroethane.

For the reaction Ph3C+ ClO4–(solv)⇌ Ph3C+(solv)+ ClO4–(solv) in 1,2-dichloroethane, the dissociation constant, (K2), ΔG°, ΔH°, and ΔS° have been calculated from conductance data.

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Article information

DOI
https://doi.org/10.1039/J19660001164
Article type
Paper

J. Chem. Soc. A, 1966, 1164-1167

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Ionisation and dissociation of trityl perchlorate in some non-aqueous solvents

W. R. Longworth and C. P. Mason, J. Chem. Soc. A, 1966, 1164 DOI: 10.1039/J19660001164

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