Precise infrared spectra of the compounds Mn2(CO)10 and Mn2(CO)8L2[L = PF3, P(OPh)3, AsPh3, PPh3, and PEt3] have been measured. Solvent effects in the C–O stretching region are observed and their significance discussed. Bands ascribed to M–C and C–O stretching vibrations correlate in the expected way.
D. J. Parker and M. H. B. Stiddard, J. Chem. Soc. A, 1966, 695 DOI: 10.1039/J19660000695
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