The bonding within M(CO)n groups (n= 1,2,3, and 4) in cylindrically symmetric environments is considered using perturbation theory. The case where n= 3, for which there is abundant structural data, is considered in detail, and the treatment is extended to molecules with non-cylindrical symmetry.
S. F. A. Kettle, J. Chem. Soc. A, 1966, 420 DOI: 10.1039/J19660000420
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