The previously known complexes of stoicheiometry M py4(NCS)2(I2)2, where M = Co or Ni, have been prepared anew, and these, and a related new compound, Ni(4-methylpyridine)4(NCS)2(I2)2, have been shown by spectroscopic studies to contain the grouping M–NCS–I–I.
D. Forster and D. M. L. Goodgame, J. Chem. Soc. A, 1966, 170 DOI: 10.1039/J19660000170
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