Spectroscopic characterization of carbon monoxide activation by neutral chromium carbides

Abstract

Spectroscopic characterization of carbon monoxide activation by neutral metal carbides is of essential importance for understanding the structure–reactivity relationships of catalytic sites, but has been proven to be very challenging owing to the difficulty in size selection. Here, we report a size-specific infrared-vacuum ultraviolet spectroscopic study of the reactions between carbon monoxide with neutral chromium carbides. Quantum chemical calculations were carried out to identify the low-lying structures and to interpret the experimental features. The results reveal that the most stable structure of CrC₃(CO)₂ consists of a CCO ketenylidene unit and that of CrC₄(CO)₂ has a semi-bridging CO with a very low CO stretching vibrational frequency at 1821 cm⁻¹. The electron structure analyses show that this semi-bridging CO is highly activated through the delocalized Cr–C–C three-center two-electron (3c–2e) interaction between the antibonding orbitals of CO and the metal carbide skeleton. The formation of these metal carbide carbonyls is found to be both thermodynamically exothermic and kinetically facile in the gas phase. The present findings have important implications for the mechanical understanding of the catalytic processes with isolated metal atoms/clusters dispersed on supports.