Isolation of uranium(III) primary phosphido complexes

Diana Perales; Rina Bhowmick; Matthias Zeller; Pere Miro; Bess Vlaisavljevich; Suzanne C. Bart

doi:10.1039/D2CC02207A

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Isolation of uranium(iii) primary phosphido complexes†

Diana Perales,^a Rina Bhowmick,

^b Matthias Zeller,^a Pere Miro,

^b Bess Vlaisavljevich

*^b and Suzanne C. Bart

*^a

Author affiliations

* Corresponding authors

^a H.C. Brown Laboratory, Department of Chemistry, Purdue University, West Lafayette, Indiana, 47907, USA
E-mail: sbart@purdue.edu

^b Department of Chemistry, University of South Dakota, Vermillion, South Dakota 57069, USA
E-mail: bess.vlaisavljevich@usd.edu

Abstract

Low-valent uranium(III) primary phosphido complexes supported by hydrotris(3,5-dimethylpyrazolyl)borate (Tp*) were synthesized with phosphines of varying steric and electronic profiles. Compounds were characterized by multinuclear NMR spectroscopy (¹H, ¹¹B, ³¹P NMR), infrared spectroscopy, electronic absorption spectroscopy, X-ray crystallography, and quantum chemical calculations.

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DOI: https://doi.org/10.1039/D2CC02207A
Article type: Communication
Submitted: 18 Apr 2022
Accepted: 25 Jul 2022
First published: 11 Aug 2022

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Chem. Commun., 2022,58, 9630-9633

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Isolation of uranium(III) primary phosphido complexes

D. Perales, R. Bhowmick, M. Zeller, P. Miro, B. Vlaisavljevich and S. C. Bart, Chem. Commun., 2022, 58, 9630 DOI: 10.1039/D2CC02207A

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Isolation of uranium(iii) primary phosphido complexes†

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Isolation of uranium(III) primary phosphido complexes

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