Issue 29, 2019

Exogenous-oxidant-free electrochemical oxidative C–H phosphonylation with hydrogen evolution

Abstract

We herein report a versatile and environmentally friendly electrochemical oxidative C–H phosphonylation protocol. This protocol features a broad substrate scope; not only C(sp2)–H phosphonylation, but also C(sp3)–H phosphonylation is tolerated well under exogenous-oxidant-free and metal catalyst-free electrochemical oxidation conditions.

Graphical abstract: Exogenous-oxidant-free electrochemical oxidative C–H phosphonylation with hydrogen evolution

Supplementary files

Article information

Article type
Communication
Submitted
02 Feb 2019
Accepted
14 Mar 2019
First published
15 Mar 2019

Chem. Commun., 2019,55, 4230-4233

Exogenous-oxidant-free electrochemical oxidative C–H phosphonylation with hydrogen evolution

Y. Yuan, J. Qiao, Y. Cao, J. Tang, M. Wang, G. Ke, Y. Lu, X. Liu and A. Lei, Chem. Commun., 2019, 55, 4230 DOI: 10.1039/C9CC00975B

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