Issue 7, 1982

Synthesis of hexakis (trimethylphosphine) molybdenum using molybdenum atoms and its X-ray crystal structure

Abstract

Co-condensation of molybdenum atoms with an excess of trimethylphosphine gives hexakis (trimethylphosphine) molybdenum which crdystal structure studies show to have an octahedral MoP6 unit; it is highly reactive to substitution by dinitrogen, olefins, and dihydrogen, forming a variety of derivatives.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1982, 393-394

Synthesis of hexakis (trimethylphosphine) molybdenum using molybdenum atoms and its X-ray crystal structure

F. G. N. Cloke, K. P. Cox, M. L. H. Green, J. Bashkin and K. Prout, J. Chem. Soc., Chem. Commun., 1982, 393 DOI: 10.1039/C39820000393

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