A temperature-reduced method for the rapid growth of hybrid perovskite single crystals with primary alcohols

Julian Höcker; Felix Brust; Melina Armer; Vladimir Dyakonov

doi:10.1039/D0CE01759K

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A temperature-reduced method for the rapid growth of hybrid perovskite single crystals with primary alcohols†

Julian Höcker,

*^a Felix Brust,^a Melina Armer

^a and Vladimir Dyakonov

^ab

Author affiliations

* Corresponding authors

^a Experimental Physics 6 and Würzburg-Dresden Cluster of Excellence ct.qmat, Julius Maximilian University of Würzburg, 97074 Würzburg, Germany
E-mail: jhoecker@physik.uni-wuerzburg.de

^b Bavarian Centre for Applied Energy Research (ZAE Bayern), Magdalene Schoch Str. 3, 97074 Würzburg, Germany

Abstract

The blends of primary alcohols and organo-lead trihalide perovskite (OLTP) precursor solutions with the stoichiometry ABX₃ (A = MA⁺ or FA⁺; B = Pb²⁺; X = Cl⁻, Br⁻ or I⁻) lead to a significant reduction in their retrograde solubilities, which enables a temperature-reduced crystallisation pathway to grow high-quality single crystals.

This article is part of the themed collection: Crystal Growth

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Article information

DOI: https://doi.org/10.1039/D0CE01759K
Article type: Communication
Submitted: 03 Dec 2020
Accepted: 10 Feb 2021
First published: 13 Feb 2021

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CrystEngComm, 2021,23, 2202-2207

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A temperature-reduced method for the rapid growth of hybrid perovskite single crystals with primary alcohols

J. Höcker, F. Brust, M. Armer and V. Dyakonov, CrystEngComm, 2021, 23, 2202 DOI: 10.1039/D0CE01759K

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CrystEngComm

A temperature-reduced method for the rapid growth of hybrid perovskite single crystals with primary alcohols†

Abstract

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A temperature-reduced method for the rapid growth of hybrid perovskite single crystals with primary alcohols

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