Formation of coordination polymer glass by mechanical milling: dependence on metal ions and molecular doping for H+ conductivity

Yuki Ohara; Akira Hinokimoto; Wenqian Chen; Takashi Kitao; Yusuke Nishiyama; You-lee Hong; Susumu Kitagawa; Satoshi Horike

doi:10.1039/C8CC02399A

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Formation of coordination polymer glass by mechanical milling: dependence on metal ions and molecular doping for H⁺ conductivity†

Yuki Ohara,^a Akira Hinokimoto,^a Wenqian Chen,^a Takashi Kitao,

^a Yusuke Nishiyama,^bc You-lee Hong,^c Susumu Kitagawa^d and Satoshi Horike

*^ade

Author affiliations

* Corresponding authors

^a Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510, Japan
E-mail: horike@icems.kyoto-u.ac.jp

^b RIKEN CLST-JEOL Collaboration Center, Tsurumi, Yokohama, Kanagawa 230-0045, Japan

^c JEOL RESONANCE Inc., 3-1-2 Musashino, Akishima, Tokyo 196-8558, Japan

^d Institute for Integrated Cell-Material Sciences (WPI-iCeMS), Institute for Advanced Study, Kyoto University, Yoshida-Honmachi, Sakyo-ku, Kyoto 606-8501, Japan

^e AIST-Kyoto University Chemical Energy Materials Open Innovation Laboratory (ChEM-OIL), Yoshida-Honmachi, Sakyo-ku, Kyoto 606-8501, Japan

Abstract

Four isostructural coordination polymer crystals having different metal ions were synthesized and studied for ball milling-induced glass formation. Distinct glass formation was discussed from crystal structures. Doping of molecules for CP glass during the milling was demonstrated, and it resulted in tunable glass properties (T_g and T_c) and enhancement of anhydrous H⁺ conductivity.

This article is part of the themed collection: 2018 Emerging Investigators

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Article information

DOI: https://doi.org/10.1039/C8CC02399A
Article type: Communication
Submitted: 26 Mar 2018
Accepted: 30 Apr 2018
First published: 01 May 2018

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Chem. Commun., 2018,54, 6859-6862

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Formation of coordination polymer glass by mechanical milling: dependence on metal ions and molecular doping for H⁺ conductivity

Y. Ohara, A. Hinokimoto, W. Chen, T. Kitao, Y. Nishiyama, Y. Hong, S. Kitagawa and S. Horike, Chem. Commun., 2018, 54, 6859 DOI: 10.1039/C8CC02399A

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Chemical Communications