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Pd-Catalyzed Ring-Opening of gem-Difluorocyclopropanes for the Mono- and Bis-fluoroallylation of 1,3-Dicarbonyls

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Rhodium Catalyzed Regioselective C−H Allylation of Simple Arenes via C−C Bond Activation of Gem‐difluorinated Cyclopropanes

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Enantioselective Tsuji‐Trost α‐Fluoroallylation of Amino Acid Esters with Gem‐Difluorinated Cyclopropanes

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Palladium/Amine Dual-Catalyzed Tsuji–Trost Fluoroallylation of Aldehydes with gem-Difluorinated Cyclopropanes

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Nitrooxylative Dearomatization Reaction of β‐Naphthols with Hypervalent Iodine Reagent

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Enantioselective Formation of All-Carbon Quaternary Stereocenters in gem-Difluorinated Cyclopropanes via Rhodium-Catalyzed Stereoablative Kinetic Resolution

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Organocatalytic Enantioselective Dearomatization of 2,3‐Disubstituted Indoles with α‐(3‐Indolyl)propargylic Alcohols

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Copper-Catalyzed Intramolecular Dearomative Arylation of Naphthylamines

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Chemo‐, Stereo‐ and Regioselective Fluoroallylation/Annulation of Hydrazones with gem‐Difluorocyclopropanes via Tunable Palladium/NHC Catalysis

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Palladium-Catalyzed Cross-Coupling of gem-Difluorocyclopropanes with gem-Diborylalkanes for the Synthesis of Boryl-Substituted Fluorinated Alkenes

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Rhodium‐Catalyzed Enantio‐ and Regioselective Allylation of Indoles with gem‐Difluorinated Cyclopropanes

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Pd/IPrBIDEA‐Catalyzed Synthesis of Pyrroles via Cascade C−C/C−F Cleavage/Annulation of gem‐Difluorocyclopropanes

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High‐Valent Copper Catalysis Enables Regioselective Fluoroarylation of Gem‐Difluorinated Cyclopropanes

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Dearomative Cyclopropanation of Naphthols via Cyclopropene Ring‐Opening

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Rhodium-Catalyzed Direct Allylation of Simple Arenes by Using Gem-Difluorinated Cyclopropanes as Allyl Surrogates

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Synthesis of α-Difluoromethylene Ethers via Photoredox-Induced Hyperconjugative Ring Opening of gem-Difluorocyclopropanes

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DFT Calculations Rationalize Unconventional Regioselectivity in PdII-Catalyzed Defluorinative Alkylation of gem-Difluorocyclopropanes with Hydrazones

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J. Org. Chem., 2024, 89, 7429
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C3-Selective Arylation of Indoles Using Palladium-Hydroxyterphenylphosphine Catalysts and Its Application to Syntheses of Nitrogen-containing Polycyclic Compounds

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Chemo‐, Stereo‐ and Regioselective Fluoroallylation/Annulation of Hydrazones with gem‐Difluorocyclopropanes via Tunable Palladium/NHC Catalysis

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Rhodium-Catalyzed Asymmetric Allylic Dearomatization of β-Naphthols with gem-Difluorinated Cyclopropanes

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Palladium-Catalyzed C–H Allylation of Electron-Deficient Polyfluoroarenes with gem-Difluorinated Cyclopropanes

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Pd-IPent-Catalyzed Defluorinative Annulation of gem-Difluorocyclopropanes with Enamides: Synthesis of Multisubstituted N-H Pyrroles

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Palladium‐Catalyzed Ring‐Opening/Defluorinative Annulation of gem‐Difluorocyclopropanes With β‐Keto Sulfones: Synthesis of Multi‐Substituted Furans

Wanqing Lu, Ge Liang, Juanjuan Wu and Leiyang Lv

Chemistry A European J, 2026
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Rhodium Catalyzed Regioselective C−H Allylation of Simple Arenes via C−C Bond Activation of Gem‐difluorinated Cyclopropanes

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Palladium‐Catalyzed Dearomative Methoxyallylation of 3‐Nitroindoles with Allyl Carbonates

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Palladium‐Catalyzed Fluorinative Bifunctionalization of Aziridines and Azetidines with gem‐Difluorocyclopropanes

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Enantioselective Tsuji‐Trost α‐Fluoroallylation of Amino Acid Esters with Gem‐Difluorinated Cyclopropanes

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Recent Advances in the Reactions of β-Naphthol at α-Position

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Palladium-Catalyzed Dearomative Fluoroallylation of Pyrroles with gem-Difluorinated Cyclopropanes

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Dearomatization of 2,3-Disubstituted Indoles via 1,8-Addition of Propargylic (Aza)-para-Quinone Methides

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Palladium‐Catalyzed Dearomative Methoxyallylation of 3‐Nitroindoles with Allyl Carbonates

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Synergistic Pd/Ni Dual-Catalyzed Cross-Coupling of Azaaryl Acetates with gem-Difluorinated Cyclopropanes

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Palladium-Catalyzed Regioselective Monofluoroallylation of Indoles with gem-Difluorocyclopropanes

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Catalytic Diversification of gem‐Difluorocyclopropanes: Recent Advances and Challenges

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Rhodium-Catalyzed Asymmetric Allylic Dearomatization of β-Naphthols with gem-Difluorocyclopropanes

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Access to gem-Diindolylcyclopropanes via Double Indolylation of gem-Difluorocyclopropanes

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Dearomative Cyclopropanation of Naphthols via Cyclopropene Ring‐Opening

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Pd-IHept-Catalyzed Ring-Opening of gem-Difluorocyclopropanes with Malonates Via Selective C–C Bond Cleavage: Synthesis of Monofluoroalkenes

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Palladium-catalyzed ring-opening defluorinative cross-coupling of gem‑difluorocyclopropanes with fluoromalonates or fluorobis(phenylsulfonyl)methane

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Carbon–Carbon Bond Cleavage for Late-Stage Functionalization

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Recent Advances in Transition-Metal-Catalyzed Cross-Coupling Reactions of gem-Difluorinated Cyclopropanes

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Site-Divergent Alkenyl C–H Fluoroallylation of Olefins Enabled by Tunable Rhodium Catalysis

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Pd/NHC-Controlled Regiodivergent Defluorinative Allylation of gem-Difluorocyclopropanes with Allylboronates

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Cobalt-Catalyzed Fluoroallyllation of Carbonyls via C–C Activation of gem-Difluorocyclopropanes

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Electrochemical 1,3‐Oxofluorination of Gem‐Difluoro Cyclopropanes: Approach to α‐CF3‐Substituted Carbonyl Compounds

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Palladium-catalyzed ring-opening/defluorinative coupling of gem-DFCPs with pyranones/pyridones

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Lewis Acid-Catalyzed Ring-Opening Cross-Coupling Reaction of gem-Difluorinated Cyclopropanes Enabled by C–F Bond Activation

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Pd/IPrBIDEA-Catalyzed Hydrodefluorination of gem-Difluorocyclopropanes: Regioselective Synthesis of Terminal Fluoroalkenes

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Ring Opening Amination of gem-Difluorocyclopropanes with Cyclobutanone Hydrazones

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Chinese Journal of Organic Chemistry, 2023, 43, 1483
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Rhodium‐Catalyzed Enantio‐ and Regioselective Allylation of Indoles with gem‐Difluorinated Cyclopropanes

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Cu/Pd-Catalyzed cis-Borylfluoroallylation of Alkynes for the Synthesis of Boryl-Substituted Monofluoroalkenes

Ayman M. Y. Suliman, Ebrahim-Alkhalil M. A. Ahmed, Tian-Jun Gong and Yao Fu

Org. Lett., 2021, 23, 3259
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Pyrroloindoline/Pyridoindoline Synthesis via C3-Dearomative Arylation/Cyclization of Tryptamine/Homotryptamine Derivatives Using Palladium–Dihydroxyterphenylphosphine Catalyst

Miyuki Yamaguchi, Ryoya Hagiwara, Hana Muto, Kanami Gayama, Hideyuki Konishi and Kei Manabe

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Nickel‐Catalyzed Regio‐ and Stereoselective Defluorinative Arylation of gem‐Difluorinated Cyclopropanes

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