Topological control in paddlewheel metal–organic cages via ligand length variation

Steven Tsoukatos; Ashakiran Maibam; Ravichandar Babarao; Witold M. Bloch

doi:10.1039/D4CC03769C

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Topological control in paddlewheel metal–organic cages via ligand length variation†

Steven Tsoukatos,

^a Ashakiran Maibam,^b Ravichandar Babarao

^bc and Witold M. Bloch

*^a

Author affiliations

* Corresponding authors

^a Institute for Nanoscale Science and Technology, College of Science and Engineering, Flinders University, Bedford Park, South Australia, Australia
E-mail: witold.bloch@Flinders.edu.au

^b School of Science, Centre for Advanced Materials and Industrial Chemistry (CAMIC), RMIT University, Melbourne, 3001 Victoria, Australia

^c CSIRO, Clayton 3168, Victoria, Australia

Abstract

Varying the length of phenanthrene-derived ligands switches the selective assembly of M^II_nL_n metal–organic cages (MOCs, n = 6 or 8) between tetrahedral, square, or triangular architectures. The limit of this approach is explored for both Cu₂ and Rh₂ paddlewheel MOCs, and supported by solution, solid-state and computational analysis.

This article is part of the themed collection: ChemComm 60th Anniversary Collection

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Article information

DOI: https://doi.org/10.1039/D4CC03769C
Article type: Communication
Submitted: 26 Jul 2024
Accepted: 25 Sep 2024
First published: 26 Sep 2024

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Chem. Commun., 2024,60, 13183-13186

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Topological control in paddlewheel metal–organic cages via ligand length variation

S. Tsoukatos, A. Maibam, R. Babarao and W. M. Bloch, Chem. Commun., 2024, 60, 13183 DOI: 10.1039/D4CC03769C

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Chemical Communications

Topological control in paddlewheel metal–organic cages via ligand length variation†

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Topological control in paddlewheel metal–organic cages via ligand length variation

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