Cp2TiCl2-catalyzed highly regioselective hydroamination of styrenes with hydroxylamines

Xuewei Luo; Sheng Wang; Chanjuan Xi

doi:10.1039/C7QO01068K

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Cp₂TiCl₂-catalyzed highly regioselective hydroamination of styrenes with hydroxylamines†

Xuewei Luo,^a Sheng Wang^a and Chanjuan Xi

*^ab

Author affiliations

* Corresponding authors

^a MOE Key Laboratory of Bioorganic Phosphorus Chemistry & Chemical Biology, Department of Chemistry, Tsinghua University, Beijing 100084, China
E-mail: cjxi@tsinghua.edu.cn

^b State Key Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin 300071, China

Abstract

A Cp₂TiCl₂-catalyzed highly regioselective hydroamination of styrene derivatives with O-benzoylhydroxylamines in the presence of isopropylmagnesium chloride to afford α-branched tertiary alkylamines in high yields has been described.

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Article information

DOI: https://doi.org/10.1039/C7QO01068K
Article type: Research Article
Submitted: 29 Nov 2017
Accepted: 29 Jan 2018
First published: 30 Jan 2018

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Org. Chem. Front., 2018,5, 1184-1187

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Cp₂TiCl₂-catalyzed highly regioselective hydroamination of styrenes with hydroxylamines

X. Luo, S. Wang and C. Xi, Org. Chem. Front., 2018, 5, 1184 DOI: 10.1039/C7QO01068K

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