Recent developments in actinide metallacycles

Abstract

All-carbon metallacycles of the d-transition metals have received widespread attention over the past three decades because of their exceptional intrinsic reactivity. However, in recent years, significant progress has also been made in the synthesis and characterization of actinide metallacyclopropenes, metallacyclopentadienes, and metallacyclocumulenes (metallacyclopentatrienes). Such actinide metallacycles are of interest because of their unique structural properties, their potential application in novel group transfer reactions and catalysis, as well as their ability to engage the 5f orbitals in metal–ligand bonding. This short review summarizes the latest developments in this area focusing on all-carbon actinide metallacycles, i.e., metallacyclopropenes, metallacyclopentadienes, and metallacyclocumulenes (metallacyclopentatrienes).