Cationic Pd(II)-catalyzed cyclization of N-tosyl-aniline tethered alkynyl ketones initiated by hydropalladation of alkynes: a facile way to 1,2-dihydro or 1,2,3,4-tetrahydroquinoline derivatives

Kun Shen; Xiuling Han; Guoqin Xia; Xiyan Lu

doi:10.1039/C4QO00286E

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Cationic Pd(ii)-catalyzed cyclization of N-tosyl-aniline tethered alkynyl ketones initiated by hydropalladation of alkynes: a facile way to 1,2-dihydro or 1,2,3,4-tetrahydroquinoline derivatives†

Kun Shen,^a Xiuling Han,*^a Guoqin Xia^a and Xiyan Lu*^a

Author affiliations

* Corresponding authors

^a State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Road, Shanghai 200032, P. R. China
E-mail: xlhan@mail.sioc.ac.cn, xylu@mail.sioc.ac.cn

Abstract

A cationic Pd(II)-catalyzed intramolecular alkyne-carbonyl reductive coupling reaction of N-tosyl-aniline tethered alkynyl ketones under transfer hydrogenation conditions to give hydroquinolines is developed.

This article is part of the themed collections: HOT articles in Organic Chemistry Frontiers in 2015 and Celebrating the 80th Birthday of Professor Ei-ichi Negishi

Download options Please wait...

Supplementary files

Article information

DOI: https://doi.org/10.1039/C4QO00286E
Article type: Research Article
Submitted: 03 Nov 2014
Accepted: 24 Dec 2014
First published: 26 Dec 2014

Download Citation

Org. Chem. Front., 2015,2, 145-149

Permissions

Request permissions

Cationic Pd(II)-catalyzed cyclization of N-tosyl-aniline tethered alkynyl ketones initiated by hydropalladation of alkynes: a facile way to 1,2-dihydro or 1,2,3,4-tetrahydroquinoline derivatives

K. Shen, X. Han, G. Xia and X. Lu, Org. Chem. Front., 2015, 2, 145 DOI: 10.1039/C4QO00286E

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Organic Chemistry Frontiers

Cationic Pd(ii)-catalyzed cyclization of N-tosyl-aniline tethered alkynyl ketones initiated by hydropalladation of alkynes: a facile way to 1,2-dihydro or 1,2,3,4-tetrahydroquinoline derivatives†

Abstract

Supplementary files

Article information

Download Citation

Permissions

Cationic Pd(II)-catalyzed cyclization of N-tosyl-aniline tethered alkynyl ketones initiated by hydropalladation of alkynes: a facile way to 1,2-dihydro or 1,2,3,4-tetrahydroquinoline derivatives

Social activity

Search articles by author

Spotlight

Advertisements