Issue 2, 2014

Magneto-chiral dichroism in chiral mixed (phthalocyaninato)(porphyrinato) rare earth triple-decker SMMs

Abstract

Two new chiral mixed (phthalocyaninato)(porphyrinato) rare earth triple-decker complexes with both (R)- and (S)-enantiomers were synthesized and structurally characterized. The significant magneto-chiral cross effect revealed for the dysprosium compound suggests the great potential of sandwich-type tetrapyrrole rare earth systems in the research field of magneto-chiral dichroism.

Graphical abstract: Magneto-chiral dichroism in chiral mixed (phthalocyaninato)(porphyrinato) rare earth triple-decker SMMs

Supplementary files

Article information

Article type
Communication
Submitted
06 Dec 2013
Accepted
14 Jan 2014
First published
27 Jan 2014

Inorg. Chem. Front., 2014,1, 167-171

Magneto-chiral dichroism in chiral mixed (phthalocyaninato)(porphyrinato) rare earth triple-decker SMMs

K. Wang, S. Zeng, H. Wang, J. Dou and J. Jiang, Inorg. Chem. Front., 2014, 1, 167 DOI: 10.1039/C3QI00097D

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