Issue 17, 2024

Ultrafast, in situ transformation of a protective layer on lithium-rich manganese-based layered oxides for high-performance Li-ion batteries

Abstract

Li-rich Mn-based layered oxides provide a compelling amalgamation of high theoretical capacity and cost-effectiveness, positioning them as prime contenders for next-generation lithium-ion battery cathodes. However, their vulnerability to surface instability gives rise to a host of challenges, notably severe capacity and voltage fading. Consequently, the surface modification of Li-rich Mn-based layered oxides emerges as a viable solution to tackle this issue. Nevertheless, current methods exhibit various drawbacks, encompassing time-intensive procedures, environmental unfriendliness, and challenges in scalability. Hence, we present a technique employing ultrafast high-temperature heating technology to dynamically reshape the chemistry and structure of the surface of individual single-crystal Li1.2Mn0.54Ni0.13Co0.13O2 cathode particles (LMLO) within a rapid 8-second timeframe. Structural analysis reveals the seamless integration of the spinel structure onto the surface, intricately linked to the internal layered structure, accompanied by a notable abundance of oxygen vacancies. Leveraging the distinctive features of this modified structure, the material demonstrates enhanced discharge capacity, superior rate performance, and prolonged cycling stability compared to the unmodified counterpart. Significantly, in stark contrast to alternative preparation methods, this technique accomplishes the formation of the protective layer within a mere 8 seconds, showcasing unparalleled efficiency. Furthermore, it boasts safety and environmental friendliness, necessitates basic instrumentation, boasts ease of operation, and is well-suited for large-scale adoption. Consequently, this method is positioned to drive the commercialization of Li-rich Mn-based layered oxide cathode materials.

Graphical abstract: Ultrafast, in situ transformation of a protective layer on lithium-rich manganese-based layered oxides for high-performance Li-ion batteries

Supplementary files

Article information

Article type
Paper
Submitted
13 May 2024
Accepted
30 Jul 2024
First published
01 Aug 2024

Green Chem., 2024,26, 9346-9356

Ultrafast, in situ transformation of a protective layer on lithium-rich manganese-based layered oxides for high-performance Li-ion batteries

Y. Yin, Y. Li, X. Hu, Z. Zou, Y. Chen, Z. Liang, L. Zhou, J. Yang and J. Wan, Green Chem., 2024, 26, 9346 DOI: 10.1039/D4GC02349H

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