Issue 64, 2020
From the journal:

Chemical Communications

Coordination distortion induced water adsorption in hydrophobic flexible metal–organic frameworks†

Yoshinobu Kamakura,a   Arata Hikawa,a   Hirofumi Yoshikawa,b   Wataru Kosaka, ORCID logo cd   Hitoshi Miyasaka ORCID logo cd  and  Daisuke Tanaka ORCID logo *ae  

* Corresponding authors

a Department of Chemistry, School of Science and Technology, Kwansei Gakuin University, 2-1 Gakuen, Sanda, Hyogo 669-1337, Japan
E-mail: dtanaka@kwansei.ac.jp

b Department of Nanotechnology for Sustainable Energy, School of Science and Technology, Kwansei Gakuin University, Sanda, Hyogo 669-1337, Japan

c Institute for Materials Research, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai 980-8577, Japan

d Department of Chemistry, Graduate School of Science, Tohoku University, 6-3 Aramaki-Aza-Aoba, Aoba-ku, Sendai 980-8578, Japan

e JST PRESTO, 2-1 Gakuen, Sanda, Hyogo 669-1337, Japan

Abstract

Herein, we synthesized four isostructural flexible interdigitated hydrophobic metal–organic frameworks that differ only in their central metal ion. The water-adsorption properties are dependent on the metal species, which was revealed to be caused by coordination distortion around the metal ions.

Graphical abstract: Coordination distortion induced water adsorption in hydrophobic flexible metal–organic frameworks

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Article information

DOI
https://doi.org/10.1039/D0CC03772A
Article type
Communication
Submitted
28 May 2020
Accepted
16 Jul 2020
First published
17 Jul 2020

Chem. Commun., 2020,56, 9106-9109

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Coordination distortion induced water adsorption in hydrophobic flexible metal–organic frameworks

Y. Kamakura, A. Hikawa, H. Yoshikawa, W. Kosaka, H. Miyasaka and D. Tanaka, Chem. Commun., 2020, 56, 9106 DOI: 10.1039/D0CC03772A

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