Emergence of electrical conductivity in a flexible coordination polymer by using chemical reduction

Kentaro Fuku; Momoka Miyata; Shinya Takaishi; Takefumi Yoshida; Masahiro Yamashita; Norihisa Hoshino; Tomoyuki Akutagawa; Hiroyoshi Ohtsu; Masaki Kawano; Hiroaki Iguchi

doi:10.1039/D0CC03062G

Emergence of electrical conductivity in a flexible coordination polymer by using chemical reduction†

Kentaro Fuku,^a Momoka Miyata,^a Shinya Takaishi,

^a Takefumi Yoshida,

^ab Masahiro Yamashita,^abc Norihisa Hoshino,

^d Tomoyuki Akutagawa,

^d Hiroyoshi Ohtsu,

^e Masaki Kawano

^e and Hiroaki Iguchi

*^a

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* Corresponding authors

^a Department of Chemistry, Graduate School of Science, Tohoku University, 6-3 Aza-Aoba, Aramaki, Sendai 980-8578, Japan
E-mail: h-iguchi@tohoku.ac.jp

^b Advanced Institute for Materials Research, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai 980-8577, Japan

^c School of Materials Science and Engineering, Nankai University, Tianjin 300350, China

^d Institute of Multidisciplinary Research for Advanced Materials, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai 980-8577, Japan

^e Department of Chemistry, School of Science, Tokyo Institute of Technology, 2-12-1 Ookayama, Meguro-ku, Tokyo 152-8550, Japan

Abstract

A flexible coordination polymer with a naphthalenediimide core exhibited reversible desorption–adsorption of solvent molecules and an enhancement of electrical conductivity (∼10⁻⁷ S cm⁻¹) upon chemical reduction using hydrazine.

This article is part of the themed collection: Functional Coordination Networks

Chemical Communications

Emergence of electrical conductivity in a flexible coordination polymer by using chemical reduction†

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Emergence of electrical conductivity in a flexible coordination polymer by using chemical reduction

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