Heterobimetallic triple-decker complexes derived from a dianionic aromatic stannole ligand

Masaichi Saito; Naoki Matsunaga; Jumpei Hamada; Shunsuke Furukawa; Mao Minoura; Susann Wegner; Juri Barthel; Christoph Janiak

doi:10.1039/C8DT01455H

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Heterobimetallic triple-decker complexes derived from a dianionic aromatic stannole ligand†‡

Masaichi Saito,

*^a Naoki Matsunaga,^a Jumpei Hamada,^a Shunsuke Furukawa,

^a Mao Minoura,^b Susann Wegner,^c Juri Barthel

^d and Christoph Janiak

Author affiliations

* Corresponding authors

^a Department of Chemistry, Graduate School of Science and Engineering, Saitama University, Shimo-okubo, Sakura-ku, Saitama-city, Saitama, Japan
E-mail: masaichi@chem.saitama-u.ac.jp

^b Department of Chemistry, College of Science, Rikkyo University, Nishi-ikebukuro, Toshima-ku, Tokyo, Japan

^c Institut für Anorganische Chemie und Strukturchemie, Heinrich-Heine-Universität Düsseldorf, Universitätsstr. 1, D-40225 Düsseldorf, Germany

^d Gemeinschaftslabor für Elektronenmikroskopie RWTH-Aachen, Ernst Ruska-Centrum für Mikroskopie und Spektroskopie mit Elektronen, Forschungszentrum Jülich GmbH, D-52425 Jülich, Germany

Abstract

A neutral heterobimetallic triple-decker stannole complex was prepared by the reaction of an anionic ruthenocene bearing a stannole dianionic ligand with [Rh(cod)Cl]₂ (cod = 1,5-cyclooctadiene), and the resulting Ru–Rh complex exhibits an electronic property different from those of the corresponding Ru–Ru and Rh–Rh complexes. The Ru–Rh complex can be decomposed in ionic liquids to metal nanoparticles.

This article is part of the themed collection: Philip Power at 65: an icon of organometallic chemistry

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Article information

DOI: https://doi.org/10.1039/C8DT01455H
Article type: Paper
Submitted: 13 Apr 2018
Accepted: 07 May 2018
First published: 10 May 2018

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Dalton Trans., 2018,47, 8892-8896

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Heterobimetallic triple-decker complexes derived from a dianionic aromatic stannole ligand

M. Saito, N. Matsunaga, J. Hamada, S. Furukawa, M. Minoura, S. Wegner, J. Barthel and C. Janiak, Dalton Trans., 2018, 47, 8892 DOI: 10.1039/C8DT01455H

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Dalton Transactions

Heterobimetallic triple-decker complexes derived from a dianionic aromatic stannole ligand†‡

Abstract

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Heterobimetallic triple-decker complexes derived from a dianionic aromatic stannole ligand

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