Issue 50, 2018
From the journal:

Chemical Communications

Intermolecular insertion reactions of azides into 9-borafluorenes to generate 9,10-B,N-phenanthrenes†

Sam Yruegas,a   Jesse J. Martineza  and  Caleb D. Martin ORCID logo *a  

* Corresponding authors

a Baylor University, Department of Chemistry and Biochemistry, One Bear Place #97348, Waco, Texas 76798, USA
E-mail: caleb_d_martin@baylor.edu

Abstract

The reactions of 9-borafluorenes with organic azides result in either the insertion of the α-nitrogen and elimination of N2 or the insertion of the γ-nitrogen to generate the corresponding phenanthrene analogues with boron and nitrogen in the 9- and 10-positions, respectively.

Graphical abstract: Intermolecular insertion reactions of azides into 9-borafluorenes to generate 9,10-B,N-phenanthrenes

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Article information

DOI
https://doi.org/10.1039/C8CC01529E
Article type
Communication
Submitted
23 Feb 2018
Accepted
09 Mar 2018
First published
09 Mar 2018

Chem. Commun., 2018,54, 6808-6811

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Intermolecular insertion reactions of azides into 9-borafluorenes to generate 9,10-B,N-phenanthrenes

S. Yruegas, J. J. Martinez and C. D. Martin, Chem. Commun., 2018, 54, 6808 DOI: 10.1039/C8CC01529E

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