From 2-methylimidazole to 1,2,3-triazole: a topological transformation of ZIF-8 and ZIF-67 by post-synthetic modification

Mustafa Erkartal; Ufuk Erkilic; Benjamin Tam; Hakan Usta; Ozgur Yazaydin; Joseph T. Hupp; Omar K. Farha; Unal Sen

doi:10.1039/C6CC08746A

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From 2-methylimidazole to 1,2,3-triazole: a topological transformation of ZIF-8 and ZIF-67 by post-synthetic modification†

Mustafa Erkartal,^a Ufuk Erkilic,

^a Benjamin Tam,^b Hakan Usta,

^a Ozgur Yazaydin,

*^b Joseph T. Hupp,*^c Omar K. Farha*^cd and Unal Sen

*^ce

Author affiliations

* Corresponding authors

^a Department of Materials Science and Nanotechnology Engineering, Abdullah Gül University, 38080 Kayseri, Turkey

^b Department of Chemical Engineering, University College London, WC1E 7JE London, UK

^c Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, IL 60208, USA
E-mail: senunal@gmail.com

^d Department of Chemistry, Faculty of Science, King Abdulaziz University, Jeddah, Saudi Arabia

^e Department of Mechanical Engineering, Abdullah Gül University, 38080 Kayseri, Turkey

Abstract

Bridging ligand replacement in zeolitic imidazolate frameworks, ZIF-8 and ZIF-67, by 1,2,3-triazole was investigated. A complete substitution of 2-methylimidazole by 1,2,3-triazole resulted in a topological transformation of the parent framework from a sodalite (SOD) network to a diamond (DIA) network.

This article is part of the themed collection: Most downloaded articles of 2017: Organic and Biological Chemistry

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Article information

DOI: https://doi.org/10.1039/C6CC08746A
Article type: Communication
Submitted: 07 Nov 2016
Accepted: 20 Jan 2017
First published: 20 Jan 2017

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Chem. Commun., 2017,53, 2028-2031

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From 2-methylimidazole to 1,2,3-triazole: a topological transformation of ZIF-8 and ZIF-67 by post-synthetic modification

M. Erkartal, U. Erkilic, B. Tam, H. Usta, O. Yazaydin, J. T. Hupp, O. K. Farha and U. Sen, Chem. Commun., 2017, 53, 2028 DOI: 10.1039/C6CC08746A

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Chemical Communications

From 2-methylimidazole to 1,2,3-triazole: a topological transformation of ZIF-8 and ZIF-67 by post-synthetic modification†

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From 2-methylimidazole to 1,2,3-triazole: a topological transformation of ZIF-8 and ZIF-67 by post-synthetic modification

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