Issue 69, 2016
From the journal:

RSC Advances

α-Iminonitrile: a new cyanating agent for the palladium catalyzed C–H cyanation of arenes†

Zhen-Bang Chen,a   Fang-Ling Zhang,a   Qing Yuan,a   Hai-Fang Chen,a   Yong-Ming Zhu*a  and  Jing-Kang Shen*b  

* Corresponding authors

a College of Pharmaceutical Sciences, Soochow University, Suzhou, China
E-mail: zhuyongming@suda.edu.cn
Fax: +86-512-67166591

b Shanghai Institute of Materia Medica, Chinese Academy of Sciences, Shanghai, China
E-mail: jkshen@mail.shcnc.ac.cn

Abstract

An efficient palladium-catalyzed C–H cyanation reaction of arenes using α-iminonitrile as a new cyanating reagent has been developed. With high regioselectivity and broad substrate scope, this reaction offers monocyanated products in moderate to excellent yields.

Graphical abstract: α-Iminonitrile: a new cyanating agent for the palladium catalyzed C–H cyanation of arenes

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Article information

DOI
https://doi.org/10.1039/C6RA14512D
Article type
Communication
Submitted
04 Jun 2016
Accepted
29 Jun 2016
First published
01 Jul 2016

RSC Adv., 2016,6, 64234-64238

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α-Iminonitrile: a new cyanating agent for the palladium catalyzed C–H cyanation of arenes

Z. Chen, F. Zhang, Q. Yuan, H. Chen, Y. Zhu and J. Shen, RSC Adv., 2016, 6, 64234 DOI: 10.1039/C6RA14512D

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