A series of 2-phosphino-1,3-diphosphonium trifluoromethanesulfonate salts has been prepared and comprehensively characterized. The compounds represent rare examples of salts containing triphosphorus dications and establish important structural and spectroscopic parameters and trends for catenated phosphorus chains.
Paul. A. Gray, Y. Carpenter, N. Burford and R. McDonald, Dalton Trans., 2016, 45, 2124 DOI: 10.1039/C5DT03116H
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