Issue 13, 2015
From the journal:

RSC Advances

A family of 3D lanthanide organic frameworks with tunable luminescence and slow magnetic relaxation†

Qipeng Liab  and  Shaowu Du*a  

* Corresponding authors

a State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, P. R. China
E-mail: swdu@fjirsm.ac.cn
Fax: +86 591 83709470

b University of Chinese Academy of Sciences, Beijing 100039, P. R. China

Abstract

A family of 3D lanthanide organic frameworks with 5-(pyridin-4-yl)isophthalic acid (H2PIP), formulated as [Ln2(PIP)3(H2O)4]·2DMF·3H2O (Ln = Sm 1, Eu 2, Gd 3, Tb 4, Dy 5 and Ho 6) have been synthesized and structurally characterized. They are isomorphous and feature a 3D 6-connected pcu topology. The tunable luminescence of 2 and 4 is investigated by changing the temperature and the variation of excitation wavelength. In addition, the slow magnetic relaxation behavior is observed in 5.

Graphical abstract: A family of 3D lanthanide organic frameworks with tunable luminescence and slow magnetic relaxation

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Article information

DOI
https://doi.org/10.1039/C4RA14939D
Article type
Paper
Submitted
20 Nov 2014
Accepted
06 Jan 2015
First published
07 Jan 2015

RSC Adv., 2015,5, 9898-9903

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A family of 3D lanthanide organic frameworks with tunable luminescence and slow magnetic relaxation

Q. Li and S. Du, RSC Adv., 2015, 5, 9898 DOI: 10.1039/C4RA14939D

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