Crystals for sustainability – structuring Al-based MOFs for the allocation of heat and cold

M. F. de Lange; C. P. Ottevanger; M. Wiegman; T. J. H. Vlugt; J. Gascon; F. Kapteijn

doi:10.1039/C4CE01073F

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Crystals for sustainability – structuring Al-based MOFs for the allocation of heat and cold†

M. F. de Lange,*^ab C. P. Ottevanger,^a M. Wiegman,^a T. J. H. Vlugt,^b J. Gascon*^a and F. Kapteijn^a

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* Corresponding authors

^a Catalysis Engineering, Chemical Engineering Department, Delft University of Technology, Julianalaan 136, 2628 BL Delft, the Netherlands
E-mail: M.F.deLange@tudelft.nl, j.gascon@tudelft.nl

^b Engineering Thermodynamics, Process & Energy laboratory, Delft University of Technology, Leeghwaterstraat 39, 2628 CB Delft, the Netherlands

Abstract

Several Al-based MOFs of the CAU family have been investigated for application in the adsorption driven allocation of heat and cold. The special water adsorption behaviour of CAU-10-H makes it ideal for application in adsorption driven heat pumps and chillers. For increased performance, CAU-10-H crystals have been grown directly on both γ-alumina and metallic aluminium. Crystal growth on these surfaces can be controlled by the addition of acids.

This article is part of the themed collection: Metal-Organic Frameworks and Hybrid Materials

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Article information

DOI: https://doi.org/10.1039/C4CE01073F
Article type: Communication
Submitted: 24 May 2014
Accepted: 18 Jul 2014
First published: 18 Jul 2014
This article is Open Access

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CrystEngComm, 2015,17, 281-285

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Crystals for sustainability – structuring Al-based MOFs for the allocation of heat and cold

M. F. de Lange, C. P. Ottevanger, M. Wiegman, T. J. H. Vlugt, J. Gascon and F. Kapteijn, CrystEngComm, 2015, 17, 281 DOI: 10.1039/C4CE01073F

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CrystEngComm

Crystals for sustainability – structuring Al-based MOFs for the allocation of heat and cold†

Abstract

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Crystals for sustainability – structuring Al-based MOFs for the allocation of heat and cold

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