Alkynide and acetonitrile activation by strained AlPC2 heterocycles

Steffi Roters; Alexander Hepp; J. Chris Slootweg; Koop Lammertsma; Werner Uhl

doi:10.1039/C2CC33300G

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Alkynide and acetonitrile activation by strained AlPC₂ heterocycles†‡

Steffi Roters,^a Alexander Hepp,^a J. Chris Slootweg,^b Koop Lammertsma*^b and Werner Uhl*^a

Author affiliations

* Corresponding authors

^a Institut für Anorganische und Analytische Chemie der Westfälischen Wilhelms-Universität Münster, Corrensstraße 30, D-48149 Münster, Germany
E-mail: uhlw@uni-muenster.de

^b Department of Chemistry and Pharmaceutical Sciences, VU University Amsterdam, De Boelelaan 1083, 1081 HV Amsterdam, The Netherlands
E-mail: k.lammertsma@vu.nl

Abstract

Bicyclic compounds with annulated four- (AlPC₂) and five-membered (P₂C₃) rings activate and capture Al-alkynides and acetonitrile at room temperature to afford bicyclic compounds with unique six-membered Al₂PC₃ and AlNPC₃ heterocycles.

This article is part of the themed collection: Frontiers in Molecular Main Group Chemistry

Download options Please wait...

Supplementary files

Article information

DOI: https://doi.org/10.1039/C2CC33300G
Article type: Communication
Submitted: 08 May 2012
Accepted: 03 Aug 2012
First published: 07 Aug 2012

Download Citation

Chem. Commun., 2012,48, 9616-9618

Permissions

Request permissions

Alkynide and acetonitrile activation by strained AlPC₂ heterocycles

S. Roters, A. Hepp, J. C. Slootweg, K. Lammertsma and W. Uhl, Chem. Commun., 2012, 48, 9616 DOI: 10.1039/C2CC33300G

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Chemical Communications