Verónica
Montes-García
a,
Cataldo
Valentini
bc,
Denys
Klymovych
a,
Wojciech
Kukułka
b,
Linghao
Shi
a,
Violetta
Patroniak
c,
Paolo
Samorì
*a and
Artur
Ciesielski
*ab
aUniversité de Strasbourg, CNRS, ISIS 8 allée Gaspard Monge, Strasbourg 67000, France. E-mail: samori@unistra.fr; ciesielski@unistra.fr
bCentre for Advanced Technologies, Adam Mickiewicz University, Uniwersytetu Poznańskiego 10, Poznań 61-614, Poland
cFaculty of Chemistry, Adam Mickiewicz University, Uniwersytetu Poznańskiego 8, Poznań 61-614, Poland
First published on 6th August 2024
Anthraquinone-based hollow COFs were synthesized via a template-assisted method involving polystyrene nanospheres as the hard template, which enabled doubling the specific capacitance and energy density compared to non-templated COFs. Our approach can be extended to other COFs, offering a promising strategy for enhancing the performance of COF-based electrodes in energy storage applications.
In this study, we synthesize hollow COFs using an anthraquinone-based COF through a template-assisted method involving PS nanospheres and assess their performance in energy storage applications. We compare the physicochemical properties and electrochemical performance of the hollow COF with those of the analogous COF synthesized in the absence of PS nanospheres. The COF synthesis involves a condensation reaction between the organic monomers 1,3,5-triformylphloroglucinol (Tp) and 2,6-diaminoanthraquinone (DAAQ), catalyzed by p-toluenesulfonic acid (PTSA), resulting in COF-DAAQ-Tp (Fig. 1a).
For the hollow COF synthesis, an analogous reaction is performed in the presence of PS nanospheres with a diameter of 300 nm, which act as a template for controlled COF growth on their surface (PS@COF-DAAQ-Tp). Subsequently, the PS nanospheres are removed via Soxhlet extraction with tetrahydrofuran (THF), yielding the hollow COF DAAQ-Tp (Fig. 1b). In imine-linked COFs, when hydroxyl groups are located next to the aldehyde moieties within one of the building units, tautomerization from the enol-imine to the keto-enamine form typically takes place. Fourier-transform infrared (FTIR) spectra (Fig. S1, ESI†) of COF-DAAQ-Tp (black curve) and hollow COF-DAAQ-Tp (red curve) provide initial evidence of successful COF syntheses and the coexistence, in both cases, of imine and β-ketoenamine forms.18 Both COFs exhibit the absence of the primary amine stretching vibration (3300–3500 cm−1) of the building unit, indicating that all the monomers have fully reacted in the synthesis process. The presence of the CN stretching vibration (1680 cm−1) confirms the imine form, while the shift of the CO stretching vibration signal to 1615 cm−1 compared to the building unit (CO around 1658 cm−1)18 and the presence of C–N stretching vibration (1250 cm−1) are indicative of β-ketoenamines.
X-ray photoelectron spectroscopy (XPS) analysis is then performed (Fig. 2a and b and Fig. S2–S4, ESI†) to gain deeper insight into the chemical composition of the as-prepared COFs. The high-resolution N 1s spectra of COF-DAAQ-Tp (Fig. 2a) and hollow COF-DAAQ-Tp (Fig. 2b) display two main peaks at 398.7 and 400 eV, which correspond to C–N (from β-ketoenamine form) and CN (from imine form) bonds, respectively. Interestingly, the content of the β-ketoenamine form is higher in the hollow COF-DAAQ-Tp. Similarly, the high-resolution O 1s spectra of COF-DAAQ-Tp (Fig. S4, ESI,† bottom panel) and hollow COF-DAAQ-Tp (Fig. S4, ESI,† top panel) exhibit two peaks at 530.9 and 532.8 eV which correspond to CO (from β-ketoenamine form) and C–O (from imine form) bonds, respectively, confirming the presence of both tautomeric forms in each COF.
Powder X-ray diffraction (PXRD) is employed to analyse the crystallinity of the COFs (Fig. S5, ESI†). Both COFs exhibit a sharp peak at 3.5°, as well as a broad peak with a maximum at 26.7°, corresponding to the reflection planes of 100, and 001 respectively, in full agreement with the simulated pattern reported in the literature (Fig. S5, ESI†).18 The PXRD analysis confirms that using a template-supported synthesis does not affect the crystalline structure of the resulting COF. Thermogravimetric analyses (TGA) (Fig. S6, ESI†) show that both COFs exhibit good thermal stability with Td10 (temperature of thermal decomposition at 10% weight) of 295 °C and 375 °C for COF-DAAQ-Tp and hollow COF-DAAQ-Tp, respectively. The higher thermal stability of hollow COF-DAAQ-Tp could be related to the higher presence of β-ketoenamine form in its structure.
Scanning (transmission) electron microscopy (S(T)EM) and high- resolution TEM (HRTEM) are used to investigate the morphology of COFs and the shell thickness of the hollow COF-DAAQ-Tp. While the SEM image of COF-DAAQ-Tp (Fig. 2c) shows the absence of any regular morphology, the SEM image of PS@COF-DAAQ-Tp (Fig. 2d) exhibits a sphere-like shape with a shell thickness of 9.40 ± 1.15 nm (Fig. S8, ESI†). Importantly, the HR-TEM images (Fig. 2e and Fig. S7b, ESI†) and STEM image (Fig. S7a, ESI†) of hollow COF-DAAQ-Tp, provide compelling evidence of the formation of a spherical hollow COF or COF shell structure, with the PS nanospheres completely etched. This observation underscores the efficacy of using PS nanospheres as a hard templating agent in guiding the morphology of the COF material.
To investigate the porosity of COF-DAAQ-Tp and hollow COF-DAAQ-Tp, nitrogen adsorption–desorption isotherms at 77 K (Fig. 2f) are acquired. These isotherms could be classified as Type IV sorption and the calculated Brunauer–Emmett–Teller (BET) surface areas amount to 257 and 344 m2 g−1 for COF-DAAQ-Tp and hollow COF-DAAQ-Tp, respectively. Additionally, the Barrett–Joyner–Haleda (BJH) model is used to calculate the pore distribution (Fig. S9, ESI†), showing a microporous nature with average pore sizes of 1.1 and 2.2 nm for COF-DAAQ-Tp and hollow COF-DAAQ-Tp, respectively. Overall, BET analysis unequivocally proves that the hollow COF demonstrates a larger surface area and higher average pore size compared to its non-templated counterpart.
The electrochemical performance of COF-DAAQ-Tp and hollow COF-DAAQ-Tp is assessed by employing them as cathode materials in zinc-ion hybrid supercapacitors (Zn-HSCs). Zn-HSCs have garnered significant interest as potential successors to current energy storage devices, lithium-ion batteries (LIBs), primarily due to their inherent safety features, cost-effectiveness, high specific capacity (820 mA h g−1), and the relatively low redox potential (−0.76 V vs. standard hydrogen electrode) of Zn anodes. A two-electrode configuration that consists of a COF-based cathode, Zn foil as anode and 4 M aqueous solution of zinc trifluoromethanesulfonate (Zn(CF3SO3)2) as electrolyte is employed. The cyclic voltammetry (CV) curves of COF-DAAQ-Tp (Fig. 3a) and hollow COF-DAAQ-Tp (Fig. 3b) COF at various scan rates (from 0.01 to 1 V s−1) in a potential window from 0 to 1.8 V show two clear peaks that correspond to the insertion/extraction processes of Zn2+ ions. In order to gain insights into the charge storage mechanism of the COF-based electrodes, the kinetics of the electrochemical processes occurring at both electrode materials are analysed using the procedure proposed by Wu et al.19 The peak current (i) correlates to the scan rate (ν) according to the eqn (4) (see ESI†). The values of b parameter define the dominating kinetics of the electrochemical process, where 0.5 corresponds to the diffusion-limited electrochemical process and 1 indicates a capacitive-limited process. The average b-values for COF-DAAQ-Tp and hollow COF-DAAQ-Tp (Fig. S10a–d, ESI†) amount to 0.81 and 0.85, respectively, indicating a hybrid storage mechanism for both COF-based electrodes, predominantly ruled by a capacitive contribution and partial diffusion-controlled contribution. To further analyse the capacitive contribution and the diffusion-controlled contribution at a specific scan rate, eqn (4) can be divided into two parts, as shown in eqn (5) (see ESI†) The capacitive and diffusion-controlled contribution values at different rates are calculated and shown in Fig. S10e and S11 (ESI†) for COF-DAAQ-Tp and Fig. S10f and S12 (ESI†) for hollow COF-DAAQ-Tp. At a scan rate of 0.01 V s−1, the capacitive contributions are 27.2% and 34.6% for COF-DAAQ-Tp and hollow COF-DAAQ-Tp, respectively. With the increase in scan rate, the capacitive contribution rises and at a scan rate of 1 V s−1 it represents 78.9% and 84.1% of the total contribution for COF-DAAQ-Tp and hollow COF-DAAQ-Tp, respectively. The higher capacitive contribution observed in the hollow COF-DAAQ-Tp, in contrast to the COF-DAAQ-Tp, may be attributed to the improved accessibility of active groups facilitated by the larger active surface area of the hollow COF-DAAQ-Tp.
Electrochemical impedance spectroscopy (EIS) is analyzed using Nyquist plots (Fig. S13, ESI†). Rct (charge transfer resistance) represents the resistance of electrochemical reactions at the electrode surface. Their values for COF-DAAQ-Tp and hollow COF-DAAQ-Tp amount to 741 and 380 Ω, respectively. The lower Rct of the hollow COF-DAAQ-Tp in comparison to the COF-DAAQ-Tp indicates a higher ionic conductivity for hollow COF-DAAQ-Tp as a result of its higher porosity.
Fig. 3c and d display the galvanostatic charge/discharge (GCD) profiles of COF-DAAQ-Tp (Fig. 3c) and hollow COF-DAAQ-Tp (Fig. 3d) in a potential window from 0 to 1.8 V at the current densities between 0.1 and 1 A g−1. The GCD profiles exhibit plateaus for both COFs, which confirms the hybrid nature of the electrode materials. The electrochemical performance is expressed by means of gravimetric capacitance, which was calculated from the GCD profiles (see ESI†).
As a result of its larger active surface area, and higher porosity, the hollow COF-DAAQ-Tp exhibits nearly twice gravimetric capacitance compared to the COF-DAAQ-Tp (142.1 versus 75.4 F g−1 at a current density of 0.1 A g−1), (Fig. 3e). Similarly, the energy density of the hollow COF-DAAQ-Tp is twice that of the COF-DAAQ-Tp (17.8 versus 8.67 W h kg−1), while power density remains similar (697.6 W kg−1 for COF-DAAQ-Tp and 603.9 W kg−1 for hollow COF-DAAQ-Tp). While hollow COF-DAAQ-Tp may not demonstrate the highest performance compared to other state-of-the-art cathode materials for Zn-HSCs (refer to Table S1, ESI†), our results emphasize that the template-assisted synthesis method significantly enhances both the electrochemical performance and the predictability of the morphological characteristics of COF materials. The long-term stability of the prepared COF-based electrodes was investigated using GCD at a current density of 1 A g−1 for 5000 charge/discharge cycles. Although the capacitance of COF-DAAQ-Tp decreases to approximately 66% after the first 50 charge/discharge cycles, the hollow COF exhibits significantly better long-term stability (capacitance retention above 70% after 5000 charge/discharge cycles) (Fig. 3f). This rapid initial decay might be associated with the formation of a solid electrolyte interphase (SEI) layer, which may form on the surface of the zinc anode.20 This enhanced stability is attributed to its higher chemical stability, as evidenced by XPS analysis, which shows a greater presence of the β-ketoenamine form in the hollow COF-DAAQ-Tp compared to the COF-DAAQ-Tp.
In summary, we successfully synthesized hollow COF shells using a template-assisted method involving PS nanospheres and an anthraquinone-based COF and evaluated their energy storage performance. The hollow COF-DAAQ-Tp exhibited a predictable spherical morphology, a larger active surface area (344 m2 g−1), and a higher average pore size (2.2 nm) compared to its non-templated counterpart (257 m2 g−1, 1.1 nm, respectively). This increased porosity improved access to the COF's carbonyl redox active sites, resulting in significantly higher electrochemical performance. Specifically, the templated COF achieved nearly double the specific capacitance (142.1 F g−1vs. 75.4 F g−1), energy density (17.8 W h kg−1vs. 8.67 W h kg−1), and a higher capacitive contribution (84.1% vs. 78.9% at 1 V s−1). Additionally, the hollow COF-DAAQ-Tp showed better long-term stability with capacitance retention above 70% after 5000 cycles, attributed to its higher chemical stability indicated by a greater presence of the β-ketoenamine form. Overall, this approach can be extended to other COFs whose building monomers are soluble in acid media (e.g., melamine, 2,5-dihydroxyterephthalaldehyde and heptaazaphenalene, to name a few) to optimize their properties, making them more suitable as electrode materials for energy storage applications.
This work was supported by the National Science Centre (grant no. 2022/47/B/ST4/02310 and 2020/36/C/ST5/00247). We also acknowledge support from the Interdisciplinary Thematic Institute SysChem via the IdEx Unistra (ANR-10-IDEX-0002) within the program Investissement d'Avenir program, the Foundation Jean-Marie Lehn and the Institut Universitaire de France (IUF).
Footnote |
† Electronic supplementary information (ESI) available. See DOI: https://doi.org/10.1039/d4cc03216k |
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