Issue 9, 2025

Thermoelectrically powered CO2 conversion in a reactive carbon electrolyzer

Abstract

Here, we use thermoelectric generators to power reactive carbon electrolyzers that upgrade captured CO2 into fuels and valuable chemicals. Reactive carbon electrolyzers convert the liquid eluent from a direct air capture unit—referred to as the “reactive carbon solution”. Thermoelectric generators convert temperature differences into electrical energy, enabling the use of waste heat to power the reactive carbon electrolyzers. This configuration enables operation without reliance on solar and wind power. We report the experimental demonstration of a thermoelectric generator powering a reactive carbon electrolyzer.

Graphical abstract: Thermoelectrically powered CO2 conversion in a reactive carbon electrolyzer

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Article information

Article type
Paper
Submitted
28 Dec 2024
Accepted
09 May 2025
First published
14 Jul 2025
This article is Open Access
Creative Commons BY-NC license

RSC Sustainability, 2025,3, 3964-3971

Thermoelectrically powered CO2 conversion in a reactive carbon electrolyzer

A. Soni, S. Ma, G. V. Crescenzo and C. P. Berlinguette, RSC Sustainability, 2025, 3, 3964 DOI: 10.1039/D4SU00826J

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