Synthesis and photoluminescent characterization of ceramic phosphors Li2MgGeO4:Ln3+ (Ln3+ = Pr3+ or Tm3+) under different excitation wavelengths

Abstract

In the current work, germanate phosphors Li₂MgGeO₄:Ln³⁺ (Ln = Pr, Tm) have been synthesized and then investigated using luminescence spectroscopy. The X-ray diffraction analysis demonstrate that ceramic compounds Li₂MgGeO₄ containing Pr³⁺ and Tm³⁺ ions crystallize in a monoclinic crystal lattice. Luminescence properties of Pr³⁺ and Tm³⁺ ions have been examined under different excitation wavelengths. The most intense blue emission band related to the ¹D₂ → ³F₄ transition of Tm³⁺ is overlaps well with broad band located near 500 nm, which is assigned to F-type centers. These effects are not evident for Pr³⁺ ions. Ceramic phosphors Li₂MgGeO₄:Ln³⁺ (Ln = Pr, Tm) are characterized based on measurements of the excitation/emission spectra and their decays. The experimental results indicate that germanate ceramics Li₂MgGeO₄ doped with trivalent rare earth ions can be applied as inorganic phosphors emitting orange (Pr³⁺) or blue (Tm³⁺) light.