Metal–organic framework-derived trimetallic oxides with dual sensing functions for ethanol

Abstract

Metal–organic framework (MOF)-derived metal oxide semiconductors have recently received extensive attention in gas sensing applications due to their high porosity and three-dimensional architecture. Still, challenges remain for MOF-derived materials, including low-cost and facile synthetic methods, rational nanostructure design, and superior gas-sensing performances. Herein, a series of Fe-MIL-88B-derived trimetallic FeCoNi oxides (FCN-MOS) with a mesoporous structure were synthesized by a one-step hydrothermal reaction followed by calcination. The FCN-MOS system consists of three main phases: α-Fe₂O₃ (n-type), CoFe₂O₄, and NiFe₂O₄ (p-type), and the nanostructure and pore size can be controlled by altering the content of α-Fe₂O₃, CoFe₂O₄, and NiFe₂O₄. The sensors based on FCN-MOS exhibit a high response of 71.9, a good selectivity towards 100 ppm ethanol at 250 °C, and long-term stability up to 60 days. Additionally, the FCN-MOS-based sensors show a p–n transition gas sensing behavior with the alteration of the Fe/Co/Ni ratio.