Issue 15, 2023
From the journal:

Dalton Transactions

Group 11 complexes with a phosphanylphosphaalkene ligand: preparation and stability study†

A. Ziółkowska, ORCID logo a   N. Szynkiewicz, ORCID logo a   J. Rylb  and  Ł. Ponikiewski ORCID logo *a  

* Corresponding authors

a Gdansk University of Technology, Chemical Faculty, Department of Inorganic Chemistry, Gabriela Narutowicza Str. 11/12, 80-233 Gdansk, Poland
E-mail: lukasz.ponikiewski@pg.edu.pl

b Gdansk University of Technology, Faculty of Applied Physics and Mathematics Institute of Nanotechnology and Materials Engineering, Gabriela Narutowicza Str. 11/12, 80-233 Gdansk, Poland

Abstract

The reactivities of two selected phosphanylphosphaalkenes, Ph2C[double bond, length as m-dash]P-PtBu2 (1a) and (p-MeO-Ph)2C[double bond, length as m-dash]P-PtBu2 (1b), toward CuCl, AgCl and (tht)AuCl (tht = tetrahydrothiophene) were investigated. As a result, new phosphanylphosphaalkene dimeric and monomeric complexes were formed (Cu and Ag dimeric and Au monomeric). All obtained products were air and moisture stable and light insensitive.

Graphical abstract: Group 11 complexes with a phosphanylphosphaalkene ligand: preparation and stability study

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Article information

DOI
https://doi.org/10.1039/D3DT00626C
Article type
Communication
Submitted
28 Feb 2023
Accepted
20 Mar 2023
First published
29 Mar 2023

Dalton Trans., 2023,52, 4658-4662

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Group 11 complexes with a phosphanylphosphaalkene ligand: preparation and stability study

A. Ziółkowska, N. Szynkiewicz, J. Ryl and Ł. Ponikiewski, Dalton Trans., 2023, 52, 4658 DOI: 10.1039/D3DT00626C

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