PEDOT:PSS-glued MoO3 nanowire network for all-solid-state flexible transparent supercapacitors

Abstract

Flexible transparent supercapacitors (FTSCs) are essential for the development of next-generation transparent electronics, however, a significant challenge is to achieve high-areal-capacitance FTSCs without sacrificing optical transparency. Herein, poly(3,4-ethylene dioxythiophene):poly(styrene sulfonate) (PEDOT:PSS)-glued MoO₃ nanowires anchored on the Ag nanofiber (AgNF) network are employed as FTSC film electrodes, in which the AgNF network provides primary conducting pathways and guarantees rapid electron transport, while wide-bandgap semiconductor MoO₃ nanowires glued by the ultrathin PEDOT:PSS layer provide abundant redox-active sites to store energy. Benefiting from the PEDOT:PSS as the conducting glue to promote the connection at the junctions between AgNFs and MoO₃ nanowires, the as-prepared AgNFs/MoO₃/PEDOT:PSS (AMP) film electrode demonstrates a high transmittance (82.8%) and large areal capacitance (15.7 mF cm⁻²), and has outperformed all the transparent conductive films known to date. Even after 11 000 charge/discharge cycles, the capacitance still remains at 92.4% of the initial value. The assembled all-solid-state FTSC device delivers an energy density of 0.623 μW h cm⁻², a power density of 40 μW cm⁻², and excellent mechanical robustness, implying a great potential in high performance FTSCs.