Phenothiazine-functionalized redox polymers for a new cathode-active material

Abstract

Redox-active, phenothiazine-functionalized polymers were synthesized and employed as a promising cathode-active material (∼3.7 V vs. Li, 77 Ah kg⁻¹) in a rechargeable battery. The longer spacer between phenothiazine and the polymer backbone contributed to the stability of the formed radical cations, resulting in decelerated self-discharge and improved cycle performance.