A monovacant heteropolytungstate-incorporated trimeric carbonyl rhenium cluster, [(AsW11O39){Re(CO)3}3(μ3-OH)(μ2-OH)]6−: synthesis, structure and catalytic properties

Yanhui Zhang; Dongdi Zhang; Zhiyuan Huo; Pengtao Ma; Jingyang Niu; Jingping Wang

doi:10.1039/C4RA03532A

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A monovacant heteropolytungstate-incorporated trimeric carbonyl rhenium cluster, [(AsW₁₁O₃₉){Re(CO)₃}₃(μ₃-OH)(μ₂-OH)]⁶⁻: synthesis, structure and catalytic properties†

Yanhui Zhang,^a Dongdi Zhang,^a Zhiyuan Huo,^a Pengtao Ma,^a Jingyang Niu*^a and Jingping Wang*^a

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* Corresponding authors

^a Key Laboratory of Polyoxometalate Chemistry of Henan Province, College of Chemistry and Chemical Engineering, Henan University, Kaifeng, Henan, China
E-mail: jyniu@henu.edu.cn, jpwang@henu.edu.cn
Fax: +86 371 23886876

Abstract

An undecatungstoarsenate-supported carbonyl rhenium derivative, [(AsW₁₁O₃₉){Re(CO)₃}₃(μ₃-OH)(μ₂-OH)]⁶⁻ (1a) has been synthesized. Polyoxoanion 1a consists of one monovacant Keggin structure unit and an unusual trimeric carbonyl rhenium cluster. It exhibits prominent catalytic activity and high selectivity in the cycloaddition of epoxides.

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Article information

DOI: https://doi.org/10.1039/C4RA03532A
Article type: Communication
Submitted: 18 Apr 2014
Accepted: 09 Jun 2014
First published: 09 Jun 2014

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RSC Adv., 2014,4, 28848-28851

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A monovacant heteropolytungstate-incorporated trimeric carbonyl rhenium cluster, [(AsW₁₁O₃₉){Re(CO)₃}₃(μ₃-OH)(μ₂-OH)]⁶⁻: synthesis, structure and catalytic properties

Y. Zhang, D. Zhang, Z. Huo, P. Ma, J. Niu and J. Wang, RSC Adv., 2014, 4, 28848 DOI: 10.1039/C4RA03532A

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