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Abstract | Cited by

High yields of epoxides were obtained in the oxidation of a large range of olefins using 1.2–2 equiv. of H2O2 in the presence of iron helmet phthalocyanines. The involvement of high-valent iron oxo species was evidenced using cryospray mass spectrometry.

Graphical abstract: Efficient epoxidation of olefins by H2O2 catalyzed by iron “helmet” phthalocyanines

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