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Abstract | Cited by

An upper rim-functionalised calix[4]arene dicarboxylic acid (H2caldc) has been used to prepare four metal–organic frameworks, three of which have been structurally characterised and shown to form two- or three-dimensional network structures. Simulations suggest that such networks are likely to display interesting selectivity to guest molecules.

Graphical abstract: Calix[4]arene-based metal–organic frameworks: towards hierarchically porous materials

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